I have asked that question several times in other threads. The key part is to focus on efforts close or above the 30 minute mark. Here is what I have found on this forum.
I have heard the guys from the "Science of the Sport" talk about the 5.8 W/kg mark. Here is their take from their website:
Andrew Coggan gave me a link of a chart for all out efforts over different periods of time. It even describes the different types of modalities behavior when going from one effort to the other. The absolute max that I can read from this table is 6.4 W/kg for prolonged efforts (well above 30 minutes). Here is the link:
http://home.trainingpeaks.com/articles/cycling/power-profiling.aspx
The only problem I have with these tables is that some numbers could have been extrapolated. I haven't had the time to ask Andrew Coggan about that. The second question is who were the riders that were tested in order to build these tables? What was their condition when they were tested. In other words, you will hope that when you assemble this type of information the riders would be completely clean and well fitted. Now, if some of the values were extrapolated then there is no way of knowing if an athlete can get to the top of the charts clean. Maybe if he is reading this he can help us understand better these tables.
Finally, JV pitched in some numbers for Bradley Wiggins well above 6 W/kg for around 20 minutes. The problem with his version is that we can not look at these numbers objectively anyway. Here is his version:
The only reliable information I can go by are the numbers pre-nineties versus after it. The only reason I say this is because of the big advantages that have been seen from the sophisticated doping programs after the nineties. There have been power numbers showing values well above 6 W/kg after the nineties but no matter how much people plea their case that the riders were clean, you just can never know.
Here is an example of a rider over 6 W/kg after the nineties:
Some forists have stated that riders like Eddy Merckx, Greg Lemond, and Bernard Hinault have barely touched the marks of 400 Watts which would put them below the 6 Watts/kg mark (I believe). I have only done the calculations for Herrera in Alpe d'Huez 1984 winner time (370-380 watts) and for Greg Lemond in the 1989 time trial (420 watts) and they were below the 6 W/kg mark. If before the nineties the power numbers show below these power numbers of 6 w/kg, then discussing whether they doped or not is a moot point. So let's no bother with that topic anyway.
Last but not least. Greg's opinion on the maximum power achievable by a clean rider:
http://www.bikeraceinfo.com/oralhistory/lemond.html