Tirreno Adriatico and Basque Country in 2022 off the top of my head. I don’t consider it a major race but he was the 2nd strongest to Pogacar last year at in the first race of the year (name slipped me) but flatted and ended up 5th.I don't remember that, but knowing how crash prone Mas is, that's not really surprising to me. It doesn't exactly speak in favor of Mas in my book, though.
Can’t remember the 3rd he crashed out in but I don’t doubt it.