Krebs' Free form/Chaos Thread

[krebs303]

 

[krebs303]

 

[krebs303]

 

[krebs303]

 

[krebs303]

 

[krebs303]

 

[usedtobefast]

nice. Krebs.

 

[usedtobefast]

he is so good. a big file.worth it i hope.

 

[Fourier]

What else do you need?

 

[L29205]

What else do you need?

cerveza por favor

 

[craig1985]

I'll see you guys down in hell.

 

[krebs303]

 

[usedtobefast]

 

[krebs303]

Two novel ruthenium polypyridine complexes, [Ru(bpy)2Cl(BPEB)](PF6) and {[Ru(bpy)2Cl]2(BPEB)}(PF6)2 (BPEB = trans-1,4-bis[2-(4-pyridyl)ethenyl]benzene), were synthesized and their characterization carried out by means of elemental analysis, UV−visible spectroscopy, positive ion electrospray (ESI-MS), and tandem mass (ESI-MS/MS) spectrometry, as well as by NMR spectroscopy and cyclic voltammetry. Cyclic and differential pulse voltammetry for the mononuclear complex showed three set of waves around 1.2 V (Ru2+/3+), −1.0 V (BPEB0/-), and −1.15 (BPEB-/2-). This complex exhibited aggregation phenomena in aqueous solution, involving π−π stacking of the planar, hydrophobic BPEB ligands. According to NMR measurements and variable-temperature experiments, the addition of β-cyclodextrin (βCD) to [Ru(bpy)2Cl(BPEB)]+ leads to an inclusion complex, breaking down the aggregated array.

 

[usedtobefast]

Two novel ruthenium polypyridine complexes, [Ru(bpy)2Cl(BPEB)](PF6) and {[Ru(bpy)2Cl]2(BPEB)}(PF6)2 (BPEB = trans-1,4-bis[2-(4-pyridyl)ethenyl]benzene), were synthesized and their characterization carried out by means of elemental analysis, UV−visible spectroscopy, positive ion electrospray (ESI-MS), and tandem mass (ESI-MS/MS) spectrometry, as well as by NMR spectroscopy and cyclic voltammetry. Cyclic and differential pulse voltammetry for the mononuclear complex showed three set of waves around 1.2 V (Ru2+/3+), −1.0 V (BPEB0/-), and −1.15 (BPEB-/2-). This complex exhibited aggregation phenomena in aqueous solution, involving π−π stacking of the planar, hydrophobic BPEB ligands. According to NMR measurements and variable-temperature experiments, the addition of β-cyclodextrin (βCD) to [Ru(bpy)2Cl(BPEB)]+ leads to an inclusion complex, breaking down the aggregated array.

 

[usedtobefast]

Two novel ruthenium polypyridine complexes, [Ru(bpy)2Cl(BPEB)](PF6) and {[Ru(bpy)2Cl]2(BPEB)}(PF6)2 (BPEB = trans-1,4-bis[2-(4-pyridyl)ethenyl]benzene), were synthesized and their characterization carried out by means of elemental analysis, UV−visible spectroscopy, positive ion electrospray (ESI-MS), and tandem mass (ESI-MS/MS) spectrometry, as well as by NMR spectroscopy and cyclic voltammetry. Cyclic and differential pulse voltammetry for the mononuclear complex showed three set of waves around 1.2 V (Ru2+/3+), −1.0 V (BPEB0/-), and −1.15 (BPEB-/2-). This complex exhibited aggregation phenomena in aqueous solution, involving π−π stacking of the planar, hydrophobic BPEB ligands. According to NMR measurements and variable-temperature experiments, the addition of β-cyclodextrin (βCD) to [Ru(bpy)2Cl(BPEB)]+ leads to an inclusion complex, breaking down the aggregated array.

open the podbay doors HAL

 

[craig1985]

 

[krebs303]

 

[krebs303]

Ok Ive done some dumb stuff but......
Tequila suicide

EDIT:Ok maybe with these two
Norwegian girls drinking tequila suicide

 

[Barrus]

Ok Ive done some dumb stuff but......
Tequila suicide

EDIT:Ok maybe with these two
Norwegian girls drinking tequila suicide

try this: tequila suicide level 2

 

[usedtobefast]

try this: tequila suicide level 2

"i don't want to sanction stupidity as a national sport..."
this what happens in places where they don't get enough sunlight
everybody knows whiskey is for snorting, jeez.

 

[krebs303]

How Not to Park Your Jet Ski

 

[krebs303]

Drinking Diet Pepsi is like going down on your cousin. Sure it tastes the same but it just ain't right.

 

[trompe le monde]

Electric Pickle

 

[flyor64]

It´s snowing here today...so:

Epic Ski Fail