btw, there is a classic rock climb in boulder, co with this name
Of Coors there is
The 99 samples were already judged not to have been kept in accounted for conditions and will not be admissable in court - no scientist will come to any firm conclusions on them.
Aside from the fact that two of the most reputable anti-doping scientists in the world have come to fairly firm conclusions on them--Ashenden and Catlin--you seem to ignore the fact that evidence in a court does not have to be black-and-white. There can be various degrees of incrimination. One can take into account that the samples may not have a fully transparent chain of custody and still regard their tests as significant.
You are certainly right that, if these samples are actually tested and the results introduced into court, LA's team will bring in some very high-powered scientists to dismiss their significance. It could get very interesting (here's a provocative scenario: following his remarks that he finds the evidence for EPO in the 99 samples convincing, Catlin is called to testify against the guy who originally wanted him to run his doping program). But if matters get that far (and not at all sure they will in what is supposed to be a fraud case), just having the samples debated will seriously damage LA's reputation. Assuming there are more positives like the '99 samples, the scientists will have to explain how long-term storage turned so many negative samples into positive ones. It's one thing to debate values that are of borderline significance. It's another to try to dismiss clear-cut positives on the grounds that they somehow changed over time.
And the platizicer test is still very new and uncertain. It could just as easily be effected by the plastic water bottles or even plastic bags they hold the blood samples within.
DEHP is used to make plastics flexible (such as PVC), and I am pretty sure is not present in the hard containers used to store small blood and urine samples. These containers do have other substances that can leach into the sample, but DEHP was chosen specifically as a component of most transfusion containers.
I will defer to someone who knows more about the actual anti-doping lab procedures (Python, probably), but I believe the minimum urine sample is supposed to be 90 ml., so 45 ml for an A or B. This amount is routinely used to carry out multiple tests, for EPO, synthetic testosterone, and other steroids. DEHP and HemAssist are possibilities. Testing for a protease would be difficult, as you would have to identify a specific amino acid sequence, and in long-term samples the protease might well be degraded to the point where even small sequences could not be reliably identified.
Frozen blood samples cannot be used to test for homologous blood doping (that’s how Tyler got off at the Olympics), but could be used to test for any chemical substance to corroborate urine tests.
I think the most fruitful lines of inquiry would be DEHP, EPO (including newer forms like CERA) and synthetic T--the last because it is apparently often used in programs involving EPO or blood transfusion. There is a lot of evidence (Tyler's doping schedules; Floyd's case) that it is often a marker for some other, more performance-enhancing substance or program. Note that since this is a court case, and the evidence does not have to black-and-white, this could be an important trial case for DEHP as a marker of blood transfusions. Just because it's not an officially validated test for doping does not mean that the science of its quantitation is not very well-established. Tests for it are used in the food industry.